岩矿测试

文章摘要

杨秀清,李厚民,李立兴,刘明军,陈靖,白云.辽宁弓长岭铁矿床磁铁矿稀土元素特征及其地质意义[J].岩矿测试,2012,31(6):1058-1066

YANG Xiu-qing,LI Hou-min,LI Li-xing,LIU Ming-jun,CHEN Jing,BAI Yun.Characteristics of Rare Earth Elements and the Geological Significance of Magnetite from Gongchangling Iron Deposit in Liaoning Province[J].Rock and Mineral Analysis,2012,31(6):1058-1066.DOI:

辽宁弓长岭铁矿床磁铁矿稀土元素特征及其地质意义

HTML 下载全文 EndNote BibTeX 查看/发表评论下载PDF阅读器

Characteristics of Rare Earth Elements and the Geological Significance of Magnetite from Gongchangling Iron Deposit in Liaoning Province

投稿时间：2012-02-21 修订日期：2012-09-20

DOI：

中文关键词: 磁铁矿稀土元素电感耦合等离子体质谱法沉积变质型铁矿弓长岭

英文关键词: magnetite rare earth elements Inductively Coupled Plasma-Mass Spectrometry sedimentary metamorphic iron deposit Gongchangling

基金项目:我国典型金属矿科学基地研究项目(20091107); 中国地质大调查项目(1212011120988); 国土资源部公益性行业专项经费项目(201111002)

作者	单位	E-mail
杨秀清	国土资源部成矿作用与资源评价重点实验室, 中国地质科学院矿产资源研究所, 北京 100037 地质过程与矿产资源国家重点实验室, 中国地质大学(北京)地球科学与资源学院, 北京 100083
李厚民	国土资源部成矿作用与资源评价重点实验室, 中国地质科学院矿产资源研究所, 北京 100037	lihoumin2002@163.com
李立兴	国土资源部成矿作用与资源评价重点实验室, 中国地质科学院矿产资源研究所, 北京 100037
刘明军	国土资源部成矿作用与资源评价重点实验室, 中国地质科学院矿产资源研究所, 北京 100037 地质过程与矿产资源国家重点实验室, 中国地质大学(北京)地球科学与资源学院, 北京 100083
陈靖	国土资源部成矿作用与资源评价重点实验室, 中国地质科学院矿产资源研究所, 北京 100037
白云	辽宁省冶金地质勘查局401队, 辽宁鞍山 114005

摘要点击次数: 2854

全文下载次数: 6196

中文摘要:

辽宁弓长岭铁矿床是我国著名的沉积变质型铁矿床,其二矿区的磁铁富矿达大型规模,属国内之最。为探讨弓长岭铁矿床铁矿的物质来源、形成环境和富矿成因,本文以二矿区六个铁矿体的贫铁矿石和富铁矿石中磁铁矿单矿物为研究对象,利用电感耦合等离子体质谱进行了系统的稀土元素测试。结果表明,所有样品中磁铁矿的稀土元素总量(∑REEs)和Y具有非常一致的特征:稀土元素总量较低,Y/Ho比值较高; 经太古界后平均澳大利亚页岩(PAAS)标准化呈现重稀土相对富集、轻稀土相对亏损的分馏模式,大部分呈现La正异常,所有样品都有明显的Eu和Y正异常,这些特征表明研究区的磁铁矿成矿物质主要来源于海底高温热液和海水; 虽然磁铁矿的Ce/Ce^*为0.69~0.97,但大多数样品缺乏真正意义的Ce负异常,这暗示其沉积于还原的海水环境; 富铁矿石磁铁矿的稀土元素总量和Eu含量明显高于贫铁矿石的磁铁矿,而且含富矿的上含铁带Eu异常明显较高,表明富铁矿石磁铁矿具有更明显的热液特征,是在贫铁矿石的基础上受热液活动形成的。

英文摘要:

The Gongchangling iron deposit is a famous diagenetic-metamorphic iron deposit in Liaoning Province. The No.2 mining area contains the largest amounts of high grade magnetite iron ore in China. In order to study the ore material source, metallogenic environment and origin of mineralization, rare earth elements (REEs) and Y of magnetites from the low grade iron ore and the high grade iron ore hosted in six ore bodies were analyzed by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The results show very similar characteristics of total contents of REEs and Y for both low grade and high grade iron ores. The total contents of REEs were very low, and Y/Ho ratios were high. After being normalized by Post Archean Australian Shale (PAAS), REEs and Y patterns displayed depletion of light REEs relative to high REEs. Most samples had positive La anomalies. All samples have distinct positive anomalies of Eu and Y. All the evidence suggests that Magnetite was derived from submarine high temperature hydrothermal fluids and sea water in the studied area. The lack of clear negative Ce anomalies in all samples indicates that magnetite was formed in an anoxic ocean, although the Ce/Ce^* ratios were 0.69-0.97. The high grade iron ore has higher concentrations of total REEs and Eu than the low grade iron ore. The upper iron ore body, which hosted high grade iron ore, also had higher anomalies of Eu, which indicates more outstanding characteristic of hydrothermal fluid. It is suggested that the high grade iron ore was formed by hydrothermal activities from low grade iron ore.

主管单位：	中国科学技术协会
主办单位：	中国地质学会岩矿测试技术专业委员会国家地质实验测试中心